The cell issue is the root of the problem and even after one

The cell issue is the root of the problem and even after one

This thesis describes the syntheses and characterisations of heterobimetallic dithiolate complexes of NiII steroids for women, PdII and CoII with FeII that derive inspiration from the chemistry and structures of the active sites of the [NiFe] hydrogenase family of metalloenzymes. These studies provide insight into the electronic structures of the Ni C and Ni L states of the [NiFe] hydrogenases and the complexes have potential as new catalysts for the production of dihydrogen.Chapter One outlines the role of dihydrogen as a potential fuel and replacement for energy sources derived from fossil fuel feedstocks. The Chapter describes the roles offered by synthetic analogues of the active sites of the [NiFe] hydrogenases as routes to meet the demand for H2 production.

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